Aplicação de óxidos de metais como catalisadores heterogêneos na isomerização da glicose em meio aquoso

Evellyn Patricia Santos da Silva; Thatiane Veríssimo dos Santos; Simoni Margareti Plentz Meneghetti

doi:10.17648/diversitas-journal-v6i1-1600

Authors

Evellyn Patricia Santos da Silva Universidade Federal de Alagoas (UFAL) https://orcid.org/0000-0002-8002-5528
Thatiane Veríssimo dos Santos Universidade Federal de Alagoas (UFAL) https://orcid.org/0000-0002-5341-5934
Simoni Margareti Plentz Meneghetti Universidade Federal de Alagoas (UFAL) https://orcid.org/0000-0003-3073-5406

DOI:

https://doi.org/10.17648/diversitas-journal-v6i1-1600

Abstract

ABSTRACT: Currently, the use of renewable and sustainablesources to produce energy and chemicalsassociatedwiththedevelopment of heterogeneous catalystsis a promisingstrategy, as theyhavetheadvantage of beingrecovered and reused, reducingcosts and contamination. In thissense, biomassderivedsugars, suchas glucose and fructose, canbeused as buildingblocks to producechemical inputs, whichcancomplementorreplace some petrochemicalderivatives and presentgreat industrial potential and high addedvalue. Thus, theisomerization of glucose to fructose in aqueousmediumwasstudiedusing metal oxides SnO₂, MoO₃ and SnO₂/MoO₃compared to thereactionwithoutcatalyst. The catalyticactivitieswereevaluated in terms of conversion and yield to fructoseattemperatures of 50 and 70ºC withreaction times of 0,25 to 6h.The catalystswerecharacterizedusingtechniquessuch as infraredabsorptionspectroscopy (FTIR), thermogravimetric analysis (TG / DTA) and X-ray diffraction (XRD). The resultsdemonstratethatthemainfactorthatinfluencesthe glucose conversion are theacidic sites present in thecatalytic systems. Withthisstudy it canbeseenthatmolybdenum oxide and mixed oxide led to high conversions, howevermolybdenum oxide showedbetterresults in terms of fructose yield. In addition, otherminorityproductssuch as glyceraldehyde and pyruvaldehydehavebeenidentified and quantified.

KEYWORDS:Biomass. Catalysis. Monosaccharides.

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Author Biographies

Evellyn Patricia Santos da Silva, Universidade Federal de Alagoas (UFAL)

Universidade Federal de Alagoas (UFAL) Campus A. C. Simões, Instituto de Química e Biotecnologia (IQB), Grupo de Catálise e Reatividade Química (GCaR). Bacharel em Química Industrial (UFAL) e discente do mestrado no Programa de Pós-Graduação em Química e Biotecnologia (PPGQB/UFAL). Maceió-AL, Brazil.

Thatiane Veríssimo dos Santos, Universidade Federal de Alagoas (UFAL)

Universidade Federal de Alagoas (UFAL) Campus A. C. Simões, Instituto de Química e Biotecnologia (IQB), Grupo de Catálise e Reatividade Química (GCaR). Mestre em Ciências (UFAL) e discente no doutorado do Programa de Pós-Graduação em Química e Biotecnologia (PPGQB/UFAL). Maceió-AL, Brazil.

Simoni Margareti Plentz Meneghetti, Universidade Federal de Alagoas (UFAL)

Universidade Federal de Alagoas (UFAL) Campus A. C. Simões, Instituto de Química e Biotecnologia (IQB), Grupo de Catálise e Reatividade Química (GCaR). Doutora em Química pela Université Louis Pasteur e docente do (IQB/UFAL). Maceió-AL, Brazil.

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